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Membrane
Technology
Osmosis
is a natural phenomenon, which is most evidently seen in transferring
of water in trees from leaves to the tree iteself. It involves
the passage of water from the section containing lower concentration
of ionic substances to a higher concentration section when
the two are separated by a semi-permeable membrane.
Membrane
technology is applied to simultaneously concentrate, fractionate
and purify any aqueous solution. The technology is based on
a combination of sieving and sorption diffusion mechanisms.
A membrane is the most important part of the technology as
it selectively separates certain species in a fluid or medium
to large sized dissolved molecules from the solution. Products
with functional properties can be produced using this process,
which are superior to products produced by conventional processes.
The criterion for selecting a membrane is the size of the
pores, which should be smaller than the size of the smallest
particle in the feed stream that is to be retained by the
membrane. Membranes have configurations such as
1. Spiral wound
2. Tubular
3.
Hollow-fiber
4.
Plate & frame
The
different configurations are meant for different applications
depending on factors like viscosity, concentration of suspended
solids, particles, size & temperature etc. A comparison of
different membranes has been provided below:
MEMBRANE
CONFIGURATION COMPARISON TABLE
|
Characteristic
|
Spiral
Wound
|
Hollow
Fibres
|
Tubular
|
Plate
& Frame
|
|
Cost
|
Low
|
Low
|
High
|
High
|
|
Packing
Density
|
High
|
UF-Good
RO-High
|
Low
|
Moderate
|
|
Operating
pressure
|
High
|
UF-Low
RO-High
|
UF-Moderate
RO-High
|
High
|
|
Membrane
Polymer Choice(UF & RO)
|
Many
|
Few
|
Few
|
Many
|
|
Fouling
Resistance
|
Fair
|
UF-Good
RO-Poor
|
Very
good
|
Fair
|
|
Cleanliness
|
Fair
|
UF-Good
RO-Poor
|
Good
|
Fair
|
Crossflow
Filtration
A very
simple process, where the pumping of the feed stream is done
to self-clean the process from solutes & solids, that are,
swept away by the pressure of the concentrate stream which
runs parallel to the surface of the membrane. The concentrated
solution is recirculated more than once in order to deplete
the feed fully. Depending upon the application & process requirement,
either the permeate or the concentration or both may become
the product.
Aqua Clear uses Spiral
wound membrane technology. Spiral membranes are
packaged in a host of ways. The spiral wound membrane element
is constructed of one or more envelopes wound around a perforated
central tube. In operation, the feed enters one end of the
membrane element under required pressure. The permeate passes
through the membrane element into the envelope & spiral inward
to central tube for collection. The retained feed is called
the concentrate and passes out of the downstream. More water
passing through the membrane results in more concentration
of solids. Spiral wound design offers the best all around
characteristic of high packing density and is rugged, which
help in high-pressure operations. This makes the technology
economical and it is one of the reasons why it is accepted
worldwide.
Reverse
Osmosis
The most
complex technique in membrane separation technology derives
its name from 'Osmosis'. If a solution is separated from a
solvent or two solutions of different concentrations are separated,
the less concentrated solution will flow towards the more
concentrated one due to its natural instinct. This is known
as 'Osmosis'. If hydraulic pressure is in excess than the
natural osmotic pressure, its application on the concentrated
solution will result in the reverse flow of the solution.
This helps extracting pure solvent from the solution and the
process is called 'Reverse Osmosis'.
Nanofiltration
A cost-effective
process it does not accept the divalent ions & low molecular
weight organics. It allows maximum monovalent ions to pass
through it. Nanofiltration membranes also remove 90% of feedwater's
hardness ions, large colour molecules and double charged scaling
ions like calcium & magnesium ions. One very common application
is the Municipal drinking water plants. The process very effectively
and efficiently concentrates either valuable or undesirable
substance from a process stream. Nanofiltration requires half
the pressure to treat a same amount of water, when compared
to other techniques.
Ultrafiltration
Ultrafiltration
is a process where a low-pressure fractionation of selected
components by size is done. The process is similar to Reverse
Osmosis. The membrane depending on the molecular weight chosen,
lets the dissolved salts & lower molecular weight materials
to pass while concentrates the high molecular weight species.
Mostly, these membranes find applications in numerous industries
for concentration & clarification of large process streams.
Microfiltration
The process
of Crossflow Microfiltration has the most open membrane and
is generally used for separating suspended solids and macro-materials
like Starch, Bacteria, Molds etc. It is a low pressure, energy
efficient process that dynamically separates micron size or
smaller particles from the liquid or gaseous feed stream.
The process has lower running costs as it operates at low
transmembrane pressure. Microfiltration is a multistage operation
with applications in effluent concentration, sterile filtration,
wine clarification etc.
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