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Membrane
Technology
Osmosis is a
natural phenomenon, which is most evidently seen in transferring
of water in trees from the leaves to the tree itself. It involves
the passage of water from the section containing lower concentration
of ionic substances to a higher concentration section when the two
are separated by a semi-permeable membrane.
Membrane
technology is applied to simultaneously concentrate, fractionate
and purify any aqueous solution. The technology is based on a combination
of sieving and sorption diffusion mechanisms. A membrane is the
most important part of the technology as it selectively separates
certain species in a fluid or medium-to-large sized dissolved molecules
from the solution. Products with functional properties can be produced
using this process, which are superior to products produced by conventional
processes. The criterion for selecting a membrane is the size of
the pores, which should be smaller than the size of the smallest
particle in the feed stream that is to be retained by the membrane.
Membranes have configurations such as
1. Spiral wound
2. Tubular
3.
Hollow-fiber
4.
Plate & frame
The
different configurations are meant for different applications depending
on factors like viscosity, concentration of suspended solids, particles,
size, temperature etc. A comparison of different membranes has been
provided below:
MEMBRANE
CONFIGURATION COMPARISON TABLE
|
Characteristic
|
Spiral
Wound
|
Hollow
Fibres
|
Tubular
|
Plate
& Frame
|
|
Cost
|
Low
|
Low
|
High
|
High
|
|
Packing
Density
|
High
|
UF-Good
RO-High
|
Low
|
Moderate
|
|
Operating
Pressure
|
High
|
UF-Low
RO-High
|
UF-Moderate
RO-High
|
High
|
|
Membrane
Polymer Choice(UF & RO)
|
Many
|
Few
|
Few
|
Many
|
|
Fouling
Resistance
|
Fair
|
UF-Good
RO-Poor
|
Very
good
|
Fair
|
|
Cleanliness
|
Fair
|
UF-Good
RO-Poor
|
Good
|
Fair
|
Crossflow
Filtration
A very simple
process, where the pumping of the feed stream is done to self-clean
the process from solutes & solids, that are swept away by the pressure
of the concentrate stream which runs parallel to the surface of
the membrane. The concentrated solution is recirculated more than
once in order to deplete the feed fully. Depending upon the application
& process requirement, either the permeate or the concentration
or both may become the product.
Aqua Clear uses Spiral wound
membrane technology. Spiral membranes are packaged in
a host of ways. The spiral wound membrane element is constructed
of one or more envelopes wound around a perforated central tube.
In operation, the feed enters one end of the membrane element under
required pressure. The permeate passes through the membrane element
into the envelope & spiral inward to central tube for collection.
The retained feed is called the concentrate and passes out of the
downstream. More water passing through the membrane results in more
concentration of solids. Spiral wound design offers the best all-around
characteristic of high packing density and is rugged, which help
in high-pressure operations. This makes the technology economical
and it is one of the reasons why it is accepted worldwide.
Reverse
Osmosis
The most complex
technique in membrane separation technology derives its name from
'Osmosis'. If a solution is separated from a solvent or two solutions
of different concentrations are separated, the less-concentrated
solution will flow towards the more concentrated one due to its
natural instinct. This is known as 'Osmosis'. If hydraulic pressure
is in excess than the natural osmotic pressure, its application
on the concentrated solution will result in the reverse flow of
the solution. This helps extracting pure solvent from the solution
and the process is called 'Reverse Osmosis'.
Nanofiltration
A cost-effective
process it does not accept the divalent ions & low molecular weight
organics. It allows maximum monovalent ions to pass through it.
Nanofiltration membranes also remove 90% of feedwater's hardness
ions, large colour molecules and double-charged scaling ions like
calcium & magnesium ions. One very common application is the municipal
drinking water plants. The process very effectively and efficiently
concentrates either valuable or undesirable substances from a process
stream. Nanofiltration requires half the pressure to treat a same
amount of water, when compared to other techniques.
Ultrafiltration
Ultrafiltration
is a process where a low-pressure fractionation of selected components
by size is done. The process is similar to Reverse Osmosis. The
membrane depending on the molecular weight chosen, lets the dissolved
salts & lower molecular weight materials to pass while it concentrates
the high molecular weight species. Mostly, these membranes find
applications in numerous industries for concentration & clarification
of large process streams.
Microfiltration
The process of
Crossflow Microfiltration has the most open membrane and is generally
used for separating suspended solids and macro-materials like Starch,
Bacteria, Molds etc. It is a low pressure, energy-efficient process
that dynamically separates micron size or smaller particles from
the liquid or gaseous feed stream. The process has lower running
costs as it operates at low transmembrane pressure. Microfiltration
is a multi-stage operation with applications in effluent concentration,
sterile filtration, wine clarification etc.
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